Reactivity of nitrosyl complexes of coii and mnii porphyrinates with reactive oxygen species putative formation of peroxynitrite intermediates

dc.contributor.guide	Mondal, Biplab
dc.coverage.spatial	Chemistry
dc.creator.researcher	Mondal, Baishakhi
dc.date.accessioned	2022-12-01T05:14:51Z
dc.date.available	2022-12-01T05:14:51Z
dc.date.awarded	2020
dc.date.completed	2020
dc.date.registered	2014
dc.description.abstract	The thesis primarily focuses on nitric oxide dioxygenase enzymes activity which converts nitric oxide toxic when overly produced to nitrate The reaction of a cobalt porphyrin complex in dichloromethane with nitric oxide NO led to the bent nitrosyl complex of CoNO 8 description It was stable in presence of oxygen gas However it reacts with H2O2 in acetonitrile or THF solution at 226 710 8217 40 194 176 C or 226 710 8217 80 194 176 C to result in the corresponding CoIII nitrate complex The reaction presumably proc...
dc.description.note	Not Available
dc.format.accompanyingmaterial	None
dc.format.dimensions	Not Available
dc.format.extent	Not Available
dc.identifier.uri	http://hdl.handle.net/10603/421300
dc.language	English
dc.publisher.institution	DEPARTMENT OF CHEMISTRY
dc.publisher.place	Guwahati
dc.publisher.university	Indian Institute of Technology Guwahati
dc.relation	Not Available
dc.rights	self
dc.source.university	University
dc.subject.keyword	Chemistry
dc.subject.keyword	Chemistry Applied
dc.subject.keyword	Physical Sciences
dc.title	Reactivity of nitrosyl complexes of coii and mnii porphyrinates with reactive oxygen species putative formation of peroxynitrite intermediates
dc.title.alternative	Not available
dc.type.degree	Ph.D.