Study of asymmetric cyanohydrin and sulfoxidation reactions and fluorometric recognition of zn2 and optically active2 substituted pyridines and fluorometric recognition of zn2 and optically active

Abstract

The thesis contains five chapters The first chapter describes the synthesis of chiral mainchain polymers bonded with R R salen and 1 4 dioctyloxybenzene as alternate segments The chapter two deals with the titanium polymer complex formation and its application for 1 2 addition of trimethylsilyl cyanide TMSCN to aldehydes The third chapter focuses on chiral titanium catalyzed asymmetric sulfoxidation with aqueous hydrogen peroxide The fourth and fifth chapters deal with the use of the pol