Influence of the ligand architecture on reactivity of high valent non heme metal intermediates

Abstract

Reactivities of the high valent non heme metal intermediates have also been investigated exhaustively in past few decades in various oxidation reactions It has also seen that the reactivities of the high valent intermediates are highly influenced by primary and secondary coordination spheres along with spin states solvents pH etc In a quest for an efficient biomimetic catalyst with high selectivity and reactivity one have to understand the factors that control reactivities of non heme metal