Site Selective C H Functionalization of Indoles Studies towards C C and C N Bond Formation
| dc.contributor.guide | Punniyamurthy, T | |
| dc.coverage.spatial | ||
| dc.creator.researcher | Banerjee, Sonbidya | |
| dc.date.accessioned | 2024-06-03T08:57:38Z | |
| dc.date.available | 2024-06-03T08:57:38Z | |
| dc.date.awarded | 2024 | |
| dc.date.completed | 2024 | |
| dc.date.registered | 2017 | |
| dc.description.abstract | The thesis is structured into four chapters. The first chapter describes a Ru-catalyzed regioselective C-N bond formation of indolines and carbazole with acyl azides via C7(sp2)-H activation followed by an intramolecular C-N bond formation for the construction of 7- aminoindoline and 1-aminocarbazole scaffolds. The second chapter deals with Cu-catalyzed C7- selective C-H/N-H cross-dehydrogenative coupling of indolines and azaindoles with sulfoximines. The third chapter demonstrates a Rh-catalyzed site-selective C7 and C6 dual C-H functionalization of indolines expending 7-azabenzonorbornaiene for the formation of functionalized pyrrolocarbazoles. The fourth chapter focuses on Pd-catalyzed weak-coordination facilitated C4- selective redox-neutral nitration of indoles with tert-butyl nitrite under aerobic oxidation catalysis. newline | |
| dc.description.note | ||
| dc.format.accompanyingmaterial | None | |
| dc.format.dimensions | ||
| dc.format.extent | ||
| dc.identifier.uri | http://hdl.handle.net/10603/568623 | |
| dc.language | English | |
| dc.publisher.institution | DEPARTMENT OF CHEMISTRY | |
| dc.publisher.place | Guwahati | |
| dc.publisher.university | Indian Institute of Technology Guwahati | |
| dc.relation | ||
| dc.rights | self | |
| dc.source.university | University | |
| dc.subject.keyword | Chemistry | |
| dc.subject.keyword | Chemistry Applied | |
| dc.subject.keyword | Physical Sciences | |
| dc.title | Site Selective C H Functionalization of Indoles Studies towards C C and C N Bond Formation | |
| dc.title.alternative | ||
| dc.type.degree | Ph.D. |
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