A study on boron nitride nanomaterials And their nanocomposites for Electrical magnetic and Surface properties
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Abstract
Boron Nitride (BN) is a ceramic material capable of withstanding
newlinevery high temperatures and has a very high bandgap. It is a polymorphic
newlinecompound made of boron and nitrogen. It exists in several different crystal
newlinestructures namely amorphous BN, hexagonal BN (hBN) and cubic BN among
newlineothers. Here the research work focuses on the varied applications in which
newlineBN plays a major role. Boron Nitride Nanotubes (BNNTs) are the center of
newlineattention in this research work. BNNTs are rolled-up variations of hBN. They
newlineare highly crystalline akin to carbon nanotubes (CNTs) but offer better
newlinethermal conductivity than CNTs. They are used in medical applications,
newlinenanocomposites and neutron shields to name a few. They can be dispersed
newlineeasily in a polymer matrix than CNTs, this property is quite rare in
newlinenanomaterials. Here, hBN in both particulate form and nanotube form were
newlineused to fabricate nanocomposites.
newlineThis research thesis is divided into three sections, each section
newlinecontaining separate works using BN nanomaterials.
newline1. BNNT synthesis and ferromagnetism in BNNTs
newlineBNNTs were synthesized by chemical vapor deposition technique
newline(CVD) at 1150 °C. The CVD technique is very simple and it offers high yield
newlineand high purity compared to other techniques such as laser ablation and arc
newlinedischarge. Elemental amorphous boron and nickel oxide were the two solid
newlineprecursors used. The synthesis was carried out in a tubular furnace, with the
newlinereactants carefully mixed in weight ratios and placed inside
newline