Synthesis and characterization of novel N-glycosylamines and β-C-glycosides based organogel

Abstract

A novel class of benzohydrazide based N-glycosylamines containing long alkyl chain newlinederivatives were synthesized in good yield and characterized using NMR (1H and 13C) newlinespectral technique. The gelation test shows that these derivatives form gels with a wide range newlineof polar (1,2-dichlorobenzene, chloroform) and non-polar (1,2-dichloroethane, toluene, newlinebenzene) solvents even with lower CGC (1.0%). Morphological studies of these glycosidic newlinegels were studied using FE-SEM, TEM and powder XRD technique. Studies further show the newlineformation of 3D self-assembled spherical and rod structures which is due to the influence of newlineorganic solvent molecules in the self-assembly. It is found that hydrogen bonding and van der newlineWaals interactions play an important role in the self-assembled structure.